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SAMs of shape-persistent macrocycles: structure and binding on HOPG and Au(111)
Authors:Borissov D  Ziegler A  Höger S  Freyland W
Institution:University of Karlsruhe, Institute of Physical Chemistry, Kaiserstrasse 12, 76128 Karlsruhe, Germany.
Abstract:Self-assembled monolayers of shape-persistent macrocycles have been adsorbed on highly oriented pyrolytic graphite and Au(111) substrates. Their structure and binding characteristics have been investigated by scanning tunneling microscopy, X-ray photoelectron spectroscopy, and ultraviolet photoelectron spectroscopy experiments. Special functionalization of the macrocycles for the first time has enabled their self-assembling and binding on a metal substrate and opened a new route for new functional nanostructures.
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