Surprising reactions of a 2H-azaphosphirene complex with a silylene |
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| Authors: | Ionescu Emanuel Gehrhus Barbara Hitchcock Peter B Nieger Martin Streubel Rainer |
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| Affiliation: | Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universit?t Bonn, Germany. |
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| Abstract: | Reaction of the 2H-azaphosphirene complex with the silylene yielded the bicyclic carbene complex as sole product at ambient temperature; the reaction was less selective at elevated temperatures; additionally, the synthesis and structure of the first 1,2,4,3-azadiphosphasilol-5-ene complex is presented. |
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