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Gd, N-codoped trititanate nanotubes: Preparation, characterization and photocatalytic activity
Authors:Haijin LiuGuoguang Liu  Guohong XieMinli Zhang  Zehua HouZhanwei He
Affiliation:a School of Chemistry and Environmental Science, Henan Normal University, Henan Key Laboratory for Environmental Pollution Control, Key Laboratory for Yellow River and Huaihe River Water Environment and Pollution Control, Ministry of Education, Xinxiang 453007, PR China
b Faculty of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, PR China
c College of Resource and Environment, Henan Institute of Science and Technology, Xinxiang 453003, PR China
Abstract:Trititanate nanotubes were prepared using hydrothermal method and then co-doped with Gd3+ and N through ion-exchanging with H+. They were characterized by X-ray photoelectron spectra (XPS), high-resolution transmission electronmicroscopy (HRTEM), X-ray diffraction (XRD), UV-vis diffusion reflection spectra (UV-vis DRS) and photoluminescence (PL) spectra. The photocatalytic activities were investigated with Rhodamine B as the model pollutant. The results indicated that synergistic reaction occurred when codoping with Gd3+ and N and the photocatalytic activities of TiO2 were enhanced significantly under visible light irradiation.
Keywords:Trititanate nanotube   Co-doping   Photocatalysis   Ion-exchange   Gadolinium   Nitrogen
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