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Superhydrophobicity of silica nanoparticles modified with polystyrene
Authors:X.L. SunZ.P. Fan  L.D. ZhangL. Wang  Z.J. WeiX.Q. Wang  W.L. Liu
Affiliation:a School of Materials Science and Engineering, Shandong Institute of Light Industry, Key Laboratory of Processing and Testing Technology of Glass Functional Ceramics of Shandong Province, Jinan 250353, PR China
b State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, PR China
Abstract:Polystyrene/silica nanoparticles were prepared by radical polymerization of silica nanoparticles possessing vinyl groups and styrene with benzoyl peroxide. The resulting vinyl silica nanoparticles, polystyrene/silica nanoparticles were characterized by means of Fourier transformation infrared spectroscopy, scanning electron microscopy and UV-vis absorption spectroscopy. The results indicated that polystyrene had been successfully grafted onto vinyl silica nanoparticles via covalent bond. The morphological structure of polystyrene/silica nanoparticles film, investigated by scanning electron microscopy, showed a characteristic rough structure. Surface wetting properties of the polystyrene/silica nanoparticles film were evaluated by measuring water contact angle and the sliding angle using a contact angle goniometer, which were measured to be 159° and 2°, respectively. The excellent superhydrophobic property enlarges potential applications of the superhydrophobic surfaces.
Keywords:Superhydrophobic surface   CB relation   Contact angle   Polystyrene   Silica nanoparticles
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