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Self-assembled tetramethylbenzidine conductive nanofibers synchronized with gold nanoparticle formation
Authors:Nguyen Dang LuongJoonsuk Oh  Youngkwan LeeJaehyun Huh  Jong Jin ParkJong Min Kim  Jae-Do Nam
Affiliation:a Gyeonggi Regional Research Center, SKKU Advanced Institute of Nanotechnology, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Ku, Suwon 440-746, South Korea
b Department of Polymer Science and Engineering, Department of Energy Science, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Ku, Suwon 440-746, South Korea
c School of Chemical Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Ku, Suwon 440-746, South Korea
d Samsung Advanced Institute of Technology (SAIT), Suwon, South Korea
Abstract:In this study, for the first time, electrically-conductive tetramethylbenzidine (TMB) nanofibers were synthesized and covered with gold nanoparticles via the in situ redox reaction of TMB and HAuCl4 in ethanol media. The gold nanoparticles were uniformly bound to the fiber surface through the coordination of the amine atoms in TMB molecules with gold nanoparticles. The conductivity of the composite fibrous membrane was found to be 2.1 × 10−3 S cm−1. The developed method described herein is simple and effective for the production of novel electrically-conductive TMB/Au nanofibers. We believed that the composite fibrous materials could be used in various fields such as optoelectronic or sensor applications.
Keywords:Fiber technology   Gold nanoparticles   Nanocomposites   Nanomaterials
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