Sunlight promoted palladium catalysed Mizoroki-Heck, Suzuki-Miyaura and Sonogashira reactions |
| |
| Authors: | Anju R. ChaudharyAshutosh V. Bedekar |
| |
| Affiliation: | Department of Chemistry, Faculty of Science, M.S. University of Baroda, Vadodara 390 002, India |
| |
| Abstract: | The palladium catalysed Mizoroki-Heck, Suzuki-Miyaura and Sonogashira reactions were successfully carried out under irradiation with sunlight. The Heck reaction gives considerable amount of Z product due to photochemical isomerization of initially formed E alkenes. Reaction of methyl 2-iodobenzoate with acrylamide under solar condition furnished 2H-2-benzazepine-1,3-dione rather than the expected derivative of cinnamate while the same reaction with ethyl 2-iodobenzoate gave the desired cinnamide. |
| |
| Keywords: | Sunlight Renewable energy Green chemistry Coupling reactions Homogeneous catalysis |
| 本文献已被 ScienceDirect 等数据库收录！ |
