Crosslinked Polystyrene Beads Modified with Sulfonyl Groups and Their Application in Aromatic/Aliphatic Hydrocarbons Separation |
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Authors: | YU Huanyang CAI Zhenzhen GUAN Jingjing SHI Zuosen CUI Zhanchen |
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Affiliation: | 1. College of Material Science and Engineering, Jilin Jianzhu University, Changchun 130118, P. R. China; 2. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China; 3. Department of Urology, the First Hospital of Jilin University, Changchun 130021, P. R. China |
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Abstract: | The separation of aromatic hydrocarbons from aromatic/aliphatic mixtures was investigated with cross- linked polystyrene(CPS) beads modified with sulfonyl groups. Three sulfonating agents, i.e. benzenesulfonyl chloride(BsCl), 4-toluene sulfonyl chloride(TsCl) and methanesulfonyl chloride(MsCl) were used to prepare sulfonyl CPS beads by Friedel-Crafts reaction. The CPS beads modified with BsCl exhibited higher sulfonation rate than those modified with MsCl and TsCl and obtained optimum selectivity in the experiments of toluene/n-heptane separation. Further separation tests with various other aromatic/aliphatic mixtures were carried out at an initial aromatic concentration of 13%(mass fraction) with the results showing that the modified beads have preferential selectivity for aromatic hydrocarbons in all aromatic/aliphatic mixtures, and especially a separation factor of 8.21 and a swelling ratio of 30% for toluene/cyclohexane system. The thermal stability and regeneration test indicate that the used polystyrene beads can be recovered through heat-drying and reused effectively. |
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Keywords: | Separation Sulfonyl Polystyrene Swelling Modification |
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