Thiophene-fused phospholo[3,2-b]phospholes and their dichalcogenides: Synthesis and structure–photophysical properties relationships |
| |
Authors: | Aiko Fukazawa Taka-aki Murai Liangchun Li Youming Chen Shigehiro Yamaguchi |
| |
Institution: | Department of Chemistry, Graduate School of Science, Nagoya University, Nagoya 464-8602, Japan |
| |
Abstract: | The PCl3-promoted intramolecular cascade cyclization produced a series of thiophene-fused phospholo3,2-b]phosphole derivatives, including non-oxidized 2, dioxides 3, and disulfides 4. These derivatives exhibit significantly red-shifted absorptions and fluorescences compared with their benzene-fused analogues. Among the thiophene-fused series, the non-oxidized 2 has the highest fluorescence quantum yield of 0.95. This trend is in contrast to that observed for the benzene analogues, in which a dioxide derivative shows the most intense fluorescence. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|