Determination of biogenic amines from electrocatalytic responses of graphite electrodes modified with metallic osmium or an osmium oxide-ruthenium cyanide film |
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Authors: | L G Shaidarova A V Gedmina I A Chelnokova G K Budnikov |
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Institution: | (1) Butlerov Institute of Chemistry, Kazan State University, ul. Kremlevskaya 18, Kazan Tatarstan, 420008, Russia |
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Abstract: | Particles of osmium or an inorganic polymeric film of osmium oxide-ruthenium cyanide (OsO-RuCN) electrodeposited on glassy carbon (GC) electrocatalyze the oxidation of dopamine (DA), adrenaline (AD), and noradrenaline (NAD). It is found that these biogenic amines are determined with a high sensitivity by oxidation at an electrode with an OsO-RuCN film. Procedures for the voltammetric determination of DA, AD, or NAD at a composite film electrode are developed. The currents of the substrate oxidation are linear functions of the concentrations in the ranges from 5 × 10?7 to 1 × 10?3 M for DA and from 1 × 10?6 to 1 × 10?3 M for AD and NAD. |
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