On the orientational properties of some one-dimensional model systems

We use the transfer matrix formalism to examine the behavior of some anisotropic hard-core fluids, the centers of whose particles are constrained to a line. At large elongation and pressure, the compressibility factorp/p is higher than that for a system with complete aligment by a factor 1+ that depends upon the molecular geometry. For molecules with a finite radius of curvature, e.g., ellipses,=d/2, while for objects with flat sides=d; hered is the number of orientational degrees of freedom. A connection is made to some recent studies of hard ellipsoid fluids. We also model the effect of an external field on physical adsorption and show the existence of a phase transition in certain limiting situations.