Total synthesis of buergerinin F and buergerinin G |
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Authors: | Han Jeong-Seok Lowary Todd L |
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Institution: | Department of Chemistry, The Ohio State University, Columbus 43210, USA. |
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Abstract: | Syntheses of buergerinin F (1) and buergerinin G (2) were carried out to establish the absolute stereochemistry of these natural products. A linear sequence was used to synthesize 1 in 15 steps and 9% overall yield from thymidine. Subsequent oxidation of 1 with ruthenium tetroxide afforded 2 in 77% yield. |
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