Synthese von ringsubstituierten Titanocen-Sulfidotetraselenid-Chelaten |
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| Authors: | Nikolaos Klouras |
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| Institution: | (1) Institut für Anorganische Chemie, Universität Patras, GR-26000 Patras, Griechenland |
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| Abstract: | Summary Reaction of the titanocene complexes (RC5H4)2Ti(SH)2, R = CH3, Si(CH3)3] with elemental selenium in refluxing carbon disulfide leads to H2S evolution and to selective formation of the titanocene sulfidotetraselenides (RC5H4)2TiSSe4. In these compounds the SSe4 chain acts as a bidentate chelating ligand. |
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| Keywords: | Titanocene sulfidotetraselenides Selenium-sulfur chelates Ringsubstituted cyclopentadienyl complexes |
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