Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex |
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Authors: | Yang Yong Rioux Robert M |
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Affiliation: | Department of Chemical Engineering, The Pennsylvania State University, 165 Fenske Laboratory, University Park, PA 16802-4400, USA. |
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Abstract: | Highly regio- and stereoselective hydrothiolation of a wide range of alkynes with various thiols was demonstrated in the presence of a well-defined Rh complex supported on mesoporous SBA-15 silica. The catalyst was easily recovered and reused several times without significant loss of activity or selectivity. |
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