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Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex
Authors:Yang Yong  Rioux Robert M
Affiliation:Department of Chemical Engineering, The Pennsylvania State University, 165 Fenske Laboratory, University Park, PA 16802-4400, USA.
Abstract:Highly regio- and stereoselective hydrothiolation of a wide range of alkynes with various thiols was demonstrated in the presence of a well-defined Rh complex supported on mesoporous SBA-15 silica. The catalyst was easily recovered and reused several times without significant loss of activity or selectivity.
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