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Cloused cycle of production of ulltrafine polytetrafluoroethylene and new areas of use of fluoropolymer manufacture waste
Authors:S L Fuks  S V Khitrin  Yu V Vologzhanina  L N Pinaeva  Yu S Mikhalitsyna  S V Devyaterikova
Institution:1.Vyatka State University,Kirov,Russia
Abstract:The features of processes of ultrafine polytetrafluoroethylene manufacture of waste technological polytetrafluoroethylene by hydrothermal method and thermal degradation with an exhaustive fluorination in the presence of cobalt trifluoride were studied. Compositions and properties of gaseous and solid products of pyrolysis and recycling in ultrafine polytetrafluoroethylene manufacture were determined. Methods of use of ultrafine polytetrafluoroethylene, gaseous products, and spent catalyst were developed. On the basis of the experiments a closed scheme of producing ultrafine polytetrafluoroethylene was proposed in view of its application with recycling of accompanying gas fraction, and separating manufacture waste with recycling of cobalt trifluoride catalyst and using the resulting cobalt difluoride for producing composite coatings and lubricants.
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