Preparation and characterization of oxoperoxo tungsten(VI) complexes with morpholinomethyl urea and related ligands |
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| Authors: | M S Pathania H N Sheikh B L Kalsotra |
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| Institution: | (1) Department of Chemistry, University of Jammu, Jammu, 180 006, India |
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| Abstract: | The monooxodiperoxo complexes of tungsten(VI) of the type WO(O2)2 L-L] (where L-L = morpholinomethyl urea, morpholinomethyl thiourea, piperidinomethyl urea, piperidinomethyl thiourea, pyrrolidinomethyl
urea, and pyrrolidinomethy thiourea) have been synthesized and characterized by elemental analysis, IR, electronic spectra,
magnetic susceptibility, and conductivity measurements, in addition to TGA/DTA. The energy-minimized structures of these complexes
have been obtained by molecular modeling using Hyperchem release 7.52.
The text was submitted by the authors in English. |
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