| Low-temperature Heat Capacities and Thermodynamic Properties of Solid State Coordination Compound Zn(nicotinate)_2·H_2O(s) |
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| 作者单位： | CHEN Jing-tao(College of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng 252059,P.R.China;Department of Chemistry,Shaanxi Educational College,Xi'an 710061,P.R.China);DI You-ying,DAN Wen-yan,HONG Yuan-ping,YANG Wei-wei,KONG Yu-xia,HE Dong-hua,TAN Zhi-cheng(College of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng 252059,P.R.China) |
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| 基金项目： | Supported by the National Natural Science Foundation of China(No.20673050);;Key Project of Science Foundation from Shaanxi Educational College of China(No.08KJ017) |
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| 摘 要： | A novel compound—monohydrated zinc nicotinate was prepared via room temperature solid phase synthesis and ball grinding.FTIR,chemical and elemental analyses and X-ray powder diffraction technique were applied to characterizing the structure and composition of the complex.Low-temperature heat capacities of the solid coordination compound were measured by a precision automated adiabatic calorimeter over a temperature range from 77 to 400 K.A solid-solid phase transition process occurred in a temperature range...
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Low-temperature Heat Capacities and Thermodynamic Properties of Solid State Coordination Compound Zn(nicotinate)2·H2O(s) |
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| CHEN Jing-tao,DI You-ying,DAN Wen-yan,HONG Yuan-ping,YANG Wei-wei,KONG Yu-xia,HE Dong-hua,TAN Zhi-cheng. Low-temperature Heat Capacities and Thermodynamic Properties of Solid State Coordination Compound Zn(nicotinate)2·H2O(s)[J]. Chemical Research in Chinese University, 2009, 25(4) |
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| Authors: | CHEN Jing-tao DI You-ying DAN Wen-yan HONG Yuan-ping YANG Wei-wei KONG Yu-xia HE Dong-hua TAN Zhi-cheng |
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| Abstract: | |
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| Keywords: | Zinc nicotinate Adiabatic calorimeter Heat capacity Phase transition Thermodynamic function |
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