Synthesis and physicochemical study of hexamminechromium(III) hexamolybdocobaltate |
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Authors: | A V Oreshkina G Z Kaziev S Holguin Quinones A D Milyutina |
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Institution: | 1272. Moscow State Pedagogical University, ul. Malaya Pirogovskaya 1, Moscow, 119899, Russia 2272. Universidad Autonoma Metropolitana Azcapotzalco, Mexico, Mexico
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Abstract: | Hexamminechromium(III) hexamolybdocobaltate Cr(NH3)6]CoMo6O18(OH)6] · 5H2O was prepared and studied by mass spectrometry, IR spectroscopy, thermogravimetry, and powder X-ray diffraction. The crystals are monoclinic: a = 11.70 Å, b = 10.69 Å, c = 15.34 Å, β = 115.04°, V = 1905.11 Å3, ρcalcd. = 1.06 g/cm3, Z = 1. |
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