| VA族元素氢化物的紫外光解和多光子电离 Ⅳ. SbH3分子的紫外激光光解和多光子电离 |
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| 引用本文： | 倪图强,马兴孝,俞书勤,孔繁敖. VA族元素氢化物的紫外光解和多光子电离 Ⅳ. SbH3分子的紫外激光光解和多光子电离[J]. 物理化学学报, 1987, 3(5): 468-473. DOI: 10.3866/PKU.WHXB19870506 |
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| 作者姓名： | 倪图强 马兴孝 俞书勤 孔繁敖 |
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| 作者单位： | Department of Modern Chemistry; The University of Science and Technology of China; Hefei; Anhui |
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| 摘 要： | 用ArF激光(193 nm)光解锑化氢, 首次获得了在波长为403-700 nm间的SbH_2发射光谱, 其辐射寿命为70±20 ns。还检测到了五十余条Sb(6s→5p)在紫外区的光谱谱线以及离子信号。它们都是多光子过程的产物。
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| 收稿时间： | 1985-11-04 |
| 修稿时间： | 1986-07-07 |
UV LASER PHOTOLYSIS AND MULTIPHOTON IONIZATION OF SbH3 |
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| Ni Tuqian,Ma Xinxiao,Yu Shuqian,Kong Fanao. UV LASER PHOTOLYSIS AND MULTIPHOTON IONIZATION OF SbH3[J]. Acta Physico-Chimica Sinica, 1987, 3(5): 468-473. DOI: 10.3866/PKU.WHXB19870506 |
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| Authors: | Ni Tuqian Ma Xinxiao Yu Shuqian Kong Fanao |
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| Affiliation: | Department of Modern Chemistry; The University of Science and Technology of China; Hefei; Anhui |
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| Abstract: | The 403-700 nm emission spectrum observed in ArF laser photolysis of stibine was recorded for the first time and was assigned to the SbH_2 (Ã~2A_1→X~2B_1) transi- tion. More than fifty emission lines arising from the transitions of Sb (6s→5p) were also observed. |
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