Energy of the frequency-elastic effect in solids

A decrease in the frequency of skeletal vibrations (frequency-elastic effect) has been measured using Raman spectroscopy, and the stretching of backbone interatomic bonds in polyethylene molecules under elastic tensile loading of oriented polyethylene fibers has been measured using X-ray diffraction. It has been found that there are differences in the sign and magnitude of the changes in the zero-point energy and the work of the external force. The energy of the frequency-elastic effect has been explained in terms of the influence exerted by the initial (before loading) anharmonic stretching of backbone bonds and the force of anharmonic pressure, with the separation of the anharmonic (potential) component of the zero-point energy of the solid. A change in the frequency of vibrations corresponds to a change in the harmonic component of the zero-point energy. The loading with an external force causes a redistribution of the zero-point energy components. An energy analysis of the loaded quantum anharmonic oscillator has confirmed the conclusion regarding the mechanism of energy transfer and revealed that, under loading, there is a redistribution of the average values of the kinetic and potential components of the internal energy of the oscillator.