Chlorination of geminal bis(alkoxy-NNO-azoxy) compounds with sodium hypochlorite |
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| Authors: | I N Zyuzin |
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| Institution: | 1. Institute of Chemical Physics Problems, Russian Academy of Sciences, pr. Akad. Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia
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| Abstract: | Chlorination of geminal bis(alkoxy-NNO-azoxy) compounds with sodium hypochlorite involves the central carbon atom and gives 1,1-bis(alkoxy-NNO-azoxy)-1-chloroalkanes with high yield. Dichlorobis-(methoxy-NNO-azoxy)methane oxidizes sodium iodide to elemental iodine. The signal from the central carbon atom in the 13C NMR spectra of bis(alkoxy-NNO-azoxy)dichloromethanes is broadened and displaced downfield relative to those of the initial compounds. |
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