Reaction of N-arylcarbamoyl-1,4-benzoquinone imines with sodium arenesulfinates |
| |
Authors: | S A Konovalova A P Avdeenko A G Sergeeva Yu V Menafova |
| |
Institution: | 1. Donbass State Engineering Academy, ul. Shkadinova 72, Kramatorsk, 84313, Ukraine
|
| |
Abstract: | N-Arylcarbamoyl-1,4-benzoquinone imines possessing at least one free ortho position with respect to the carbonyl carbon atom in the quinoid ring react with sodium arenesulfinates according to the nucleophilic 1,4-addition pattern with complete regioselectivity. If both ortho positions are occupied, the reaction gives a mixture of products where the major ones are 1,6- and 6,1-adducts formed according to the radical ion mechanism. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|