Synthesis and aminolysis of N-(bicyclo[2.2.1]hept-5-en-endo-2-ylmethyl)-N-(oxiran-2-ylmethyl)(7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonamide |
| |
Authors: | V. A. Pal’chikov S. A. Prid’ma L. I. Kas’yan |
| |
Affiliation: | 1. Oles Honchar Dnipropetrovsk National University, pr. Gagarina 72, Dnipropetrovsk, 49010, Ukraine
|
| |
Abstract: | A new N-(oxiran-2-ylmethyl) (glycidyl) derivative has been obtained by reaction of N-(bicyclo-[2.2.1]hept-5-en-endo-2-ylmethyl)(7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonamide with epichlorohydrin. Its epoxidation and aminolysis have been studied, and the regioselectivity of these transformations has been determined by IR and 1H NMR spectroscopy and mass spectrometry. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|