Organosilicon polymers based on polyvinylsilsesquioxane and sulfenyl chlorides of metal acetylacetonates |
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| Authors: | N P Shapkin E I Karpova M V Tutov |
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| Institution: | 1. Far Eastern Federal University, ul. Sukhanova 8, Vladivostok, 690091, Russia
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| Abstract: | Addition of sulfenyl chlorides of metal acetylacetonates to poly(vinylsilsesquioxane) followed by addition of vinyltributylsilane has yielded polymers containing metal chelate fragments. The metal complex addition has been studied at varied ratio of the reagents; the highest reached conversion of vinyl groups is 60%. |
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