Reaction of secondary phosphine chalcogenides with diallylamine |
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Authors: | S. I. Verkhoturova T. I. Kazantseva S. N. Arbuzova A. I. Albanov N. K. Gusarova B. A. Trofimov |
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Affiliation: | 1. A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia
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Abstract: | Diphenyl- or bis(2-phenylethyl)phosphine sulfides and -phosphine selenides react with diallylamine under radical initiation (UV or AIBN) to afford the corresponding diadducts and tetrahydropyrrolylmethyl phosphine chalcogenides. The yield and the ratio of the products depend on the structure of the starting secondary phosphine chalcogenides. |
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