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| 2,6-二氨基-3,5-二硝基吡啶-1-氧化物的合成新方法 | |
| 引用本文： | 成健,姚其正,周新利,杜扬,方东,刘祖亮. 2,6-二氨基-3,5-二硝基吡啶-1-氧化物的合成新方法[J]. 有机化学, 2008, 28(11): 1943-1947 |
| 作者姓名： | 成健 姚其正 周新利 杜扬 方东 刘祖亮 |
| 作者单位： | 1. 南京理工大学化工学院,南京,210094 2. 中国药科大学药学院,南京,210094 |
| 摘 要： | 研究了2,6-二氨基-3,5-二硝基吡啶-1-氧化物(ANPyO)的合成新方法. 以2,6-二氨基吡啶为起始原料, 经酰基化、N-氧化、硝化三步反应得到ANPyO, 总收率为75%. 测试了ANPyO的爆速、爆压、DSC, 以及电火花感度和落锤感度, 同1,3,5-三氨基-2,4,6-三硝基苯(TATB)的性能进行了对比, 结果表明ANPyO综合性能和TATB基本相当. 用1H NMR, MS和红外光谱对ANPyO及其中间体结构进行了表征. |
| 关 键 词： | 2,6-二氨基-3,5-二硝基吡啶-1-氧化物 1,3,5-三氨基-2,4,6-三硝基苯 合成 性能 |
| 收稿时间： | 2008-04-01 |
| 修稿时间： | 2008-04-28 |
Novel Synthesis of 2,6-Diamino-3,5-dinitropyridine-1-oxide |
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| CHENG,Jian,YAO,Qi-Zheng,ZHOU,Xin-Li,DU,Yang,FANG,Dong,LIU,Zu-Liang. Novel Synthesis of 2,6-Diamino-3,5-dinitropyridine-1-oxide[J]. Chinese Journal of Organic Chemistry, 2008, 28(11): 1943-1947 | |
| Authors: | CHENG Jian YAO Qi-Zheng ZHOU Xin-Li DU Yang FANG Dong LIU Zu-Liang |
| Affiliation: | (a School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094) (b School of Pharmacy, China Pharmaceutical University, Nanjing 210094) |
| Abstract: | A novel synthetic method of 2,6-diamino-3,5-dinitropyridine-1-oxide (ANPyO) was explored using 2,6-diaminopyridine as the starting materials in three steps, including acetylation, N-oxidation and ni- tration. Thus, the overall yield of ANPyO was up to 75%. Detonation velocity, detonation pressure, DSC and sensitivities of electrospark and impact for ANPyO were measured, showing that ANPyO and 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) are almost equal in overall performance. |
| Keywords: | 2 6-diamino-3 5-dinitropyridine-1-oxide 1 3 5-triamino-2 4 6-trinitrobenzene synthesis per- formance |
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