Synthesis of Secondary Alcohols and Their Esters from 4-Alkoxy-4-acetyl-1-(2-ethoxyethyl)piperidines |
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Authors: | K D Praliev I A Poplavskaya B Zh Nauyryzova M A Baimurzina K D Botbaeva |
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Institution: | (1) Bekturov Institute of Chemical Sciences, National Academy of Sciences of Kazakhstan, Almaty, Kazakhstan |
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Abstract: | 4-Alkoxy-4-(1-hydroxyethyl)-1-(2-ethoxyethyl)piperidines were prepared by reduction of 4-alkoxy-4-acetyl-1-(2-ethoxyethyl)piperidines. The esters of the hydroxyethyl derivatives were prepared. The presence of an asymmetric carbon atom in the molecules of the carbinols and their esters results in complication of their 1H NMR spectra.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 3, 2005, pp. 456–460.Original Russian Text Copyright © 2005 by Praliev, Poplavskaya, Nauyryzova, Baimurzina, Botbaeva. |
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