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2-Aza-1,3-butadiene derivatives featuring an anthracene or pyrene unit: highly selective colorimetric and fluorescent signaling of Cu2+ cation
Authors:Martínez Rosario  Zapata Fabiola  Caballero Antonio  Espinosa Arturo  Tarraga Alberto  Molina Pedro
Institution:Departamento de Química Organica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, E-30100 Murcia, Spain.
Abstract:Structure: see text] A new probe based on an anthryl derivative bearing an azadiene side chain selectively senses Cu2+ in acetonitrile through two different channels: the yellow-to-orange color change and a remarkable enhancement of the fluorescence, whereas the pyrenyl analogous behaves as a fluorescent sensor for Cu2+ and Hg2+ in aqueous environment.
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