Structural transformations in dinuclear zinc complexes involving Zn-Zn bonds |
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| Authors: | Tsai Yi-Chou Lu Duan-Yen Lin Yang-Miin Hwang Jenn-Kang Yu Jen-Shiang K |
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| Institution: | Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan, R.O.C. yictsai@mx.nthu.edu.tw |
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| Abstract: | Reduction of Zn(2)(mu-eta(2)-Me(2)Si(NDipp)(2))(2) with 4 equiv. of KC(8) resulted in a dramatic structural transformation into (eta(2)-Me(2)Si(NDipp)(2))ZnZn(eta(2)-Me(2)Si(NDipp)(2))](2-) featuring a Zn-Zn bond instead of Zn(2)(micro-eta(2)-Me(2)Si(NDipp)(2))(2)](2-); the mechanism of the observed structural transformations arising from the Zn-Zn bond formation involving the intermediate of Zn(2)(mu-eta(2)-Me(2)Si(NDipp)(2))(2)](-) was elucidated by elaborate computations. |
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