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An organotransition-metal complex with pentagonal-pyramidal structure |
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| Authors: | García-Monforte M Angeles Baya Miguel Falvello Larry R Martín Antonio Menjón Babil |
| Institution: | Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-C.S.I.C. C/Pedro Cerbuna 12, 50009 Zaragoza (Spain). |
| Abstract: | Star gazing: The six-coordinate organoniobium(V) compound NBu(4) ](2) NbO(C(6) F(5) )(5) ] has been found to exhibit a pentagonal-pyramidal (PPY-6) structure, which is unprecedented in organotransition-metal chemistry (see picture: complex as viewed down the O-Nb axis; C in gray, O in red, F in yellow, and Nb in blue). |
| Keywords: | hypovalent compounds niobium non‐VSEPR structures organometallic compounds pentagonal‐pyramidal structures |
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