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A simple approach to room temperature phosphorescent allenylidene complexes |
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| Authors: | Kessler Florian Curchod Basile F E Tavernelli Ivano Rothlisberger Ursula Scopelliti Rosario Di Censo Davide Grätzel Michael Nazeeruddin Md Khaja Baranoff Etienne |
| Affiliation: | Laboratory of Photonics and Interfaces, Institute of Chemical Sciences and Engineering, école Polytechnique Fédérale de Lausanne, 1015 Lausanne (Switzerland). |
| Abstract: | A warm (blue) glow: A stable bis-cyclometalated iridium(III) allenylidene complex is prepared from a bis-cyclometalated iridium(III) complex. This strategy gives the first allenylidene complex that is phosphorescent at room temperature. |
| Keywords: | alkynyl complexes allenylidene complexes carbenes cumulenes phosphorescent iridium complexes |
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