| 用于环酯单体开环聚合的无金属引发/催化体系 |
| |
| 引用本文： | 刘继延,张黎明.用于环酯单体开环聚合的无金属引发/催化体系[J].化学进展,2007(Z1). |
| |
| 作者姓名： | 刘继延 张黎明 |
| |
| 作者单位： | 江汉大学化学与环境工程学院，中山大学化学与化学工程学院 武汉430056，中山大学化学与化学工程学院广州510275，广州510275 |
| |
| 基金项目： | 国家自然科学基金项目资助(No.30470476) |
| |
| 摘 要： | 环酯单体在不同引发/催化体系作用下的开环聚合是制备可生物降解脂肪族聚酯的主要方法。综述了近年来用于环酯单体开环聚合的无金属引发/催化体系,主要涉及水、醇、胺、羧酸等引发剂及质子酸、膦类、氮杂环类化合物等催化剂体系。
|
| 关 键 词： | 环酯单体 开环聚合 无金属引发剂 催化剂 脂肪族聚酯 |
Metal-Free Initiator /Catalyst Systems for the Ring Opening Polymerization of Cyclic Ester Monomers |
| |
| Liu Jiyan.Metal-Free Initiator /Catalyst Systems for the Ring Opening Polymerization of Cyclic Ester Monomers[J].Progress in Chemistry,2007(Z1). |
| |
| Authors: | Liu Jiyan |
| |
| Abstract: | The ring opening polymerization(ROP) of cyclic ester monomers in the presence of various initiator/catalyst systems is a main approach for the preparation of biodegradable aliphatic polyesters.The recent progress of metal-free initiator/catalyst systems used for the ROP of cyclic ester monomers is reviewed,including H_2O,alcohol,amine,and carboxylic acid initiators,as well as proton acid,phosphine and N-heterocycle catalysts. |
| |
| Keywords: | cyclic ester monomers ring opening polymerization metal-free initiators catalysts aliphatic polyesters |
| 本文献已被 CNKI 等数据库收录！ |
