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Synthesis and Gas Adsorption Properties of Tetra‐Armed Microporous Organic Polymer Networks Based on Triphenylamine
Authors:Xiao Yang  Shuwen Yao  Miao Yu  Jia‐Xing Jiang
Abstract:Two novel tetra‐armed microporous organic polymers have been designed and synthesized via a nickel‐catalyzed Yamamoto‐type Ullmann cross‐coupling reaction or Suzuki cross‐coupling polycondensation. These polymers are stable in various solvents, including concentrated hydrochloric acid, and are thermally stable. The homocoupled polymer YPTPA shows much higher Brunauer–Emmet–Teller‐specific surface area up to 1557 m2 g?1 than the copolymer SPTPA (544 m2 g?1), and a high CO2 uptake ability of 3.03 mmol g?1 (1.13 bar/273 K) with a CO2/N2 sorption selectivity of 17.3:1. Both polymers show high isosteric heats of CO2 adsorption (22.7–26.5 kJ mol?1) because the incorporation of nitrogen atoms into the skeleton of microporous organic polymers enhances the interaction between the pore wall and the CO2 molecules. The values are higher than those of the porous aromatic frameworks, which contain neither additional polar functional groups nor nitrogen atoms, and are rather close to those of previously reported microporous organic polymers containing the nitrogen atoms on the pore wall. These data show that these materials would be potential candidates for applications in post‐combustion CO2 capture and sequestration technology.
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Keywords:carbon dioxide capture and storage  heat of sorption  microporous organic polymer  nitrogen‐rich polymer network
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