Synthesis and magnetic properties of single-crystalline BaFe12O19 nanoparticles |
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Authors: | Jiangying Yu Shaolong Tang Lin Zhai Yangguang Shi Youwei Du |
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Institution: | aNanjing National Laboratory of Microstructures, Jiangsu Provincial Laboratory for Nanjing University, and Department of Physics, Nanjing University, 22 Hankou Road, Nanjing 210093, China;bDepartment of Mathematics and Physics, Anhui Institute of Architecture and Industry, Hefei 230022, China |
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Abstract: | Rod-like and platelet-like nanoparticles of simple-crystalline barium hexaferrite (BaFe12O19) have been synthesized by the molten salt method. Both particle size and morphology change with the reaction temperature and time. The easy magnetization direction (0 0 l) of the BaFe12O19 nanoparticles has been observed directly by performing X-ray diffraction on powders aligned at 0.5 T magnetic field. The magnetic properties of the BaFe12O19 magnet were investigated with various sintering temperatures. The maximum values of saturation magnetization (σs=65.8 emu/g), remanent magnetization (σr=56 emu/g) and coercivity field (Hic=5251 Oe) of the aligned samples occurred at the sintering temperatures of 1100 °C. These results indicate that BaFe12O19 nanoparticles synthesized by the molten salt method should enable detailed investigation of the size-dependent evolution of magnetism, microwave absorption, and realization of a nanodevice of magnetic media. |
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Keywords: | BaFe12O19 Molten salt Nanomaterials Magnetocrystalline anisotropy |
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