| 二(三苯基膦)水杨酸铜(Ⅰ)乙醇溶剂配合物的晶体结构 |
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| 引用本文： | 建方方,肖海连,孙萍萍.二(三苯基膦)水杨酸铜(Ⅰ)乙醇溶剂配合物的晶体结构[J].无机化学学报,2003,19(8). |
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| 作者姓名： | 建方方 肖海连 孙萍萍 |
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| 作者单位： | 青岛科技大学新材料与功能配合物实验室,青岛,266042 |
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| 基金项目： | 山东省自然科学基金，山东省教育厅资助项目 |
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| 摘 要： |
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| 关 键 词： | 三苯基膦配体 晶体结构 Cu(Ⅰ)配合物 三角形 氢键 triphenylphosphine ligand crystal structure copper (Ⅰ) complex trigonal geometryhydrogen bond |
Crystal Structure of Bis(triphenylphosphine) Copper (Ⅰ) hydroxylbenzoate Ethanol Solvate: [(PPh3)2Cu(O2CPhOH)]·CH3CH2OH |
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| Abstract: | The crystal and molecular structure of (PPh3)2Cu(O2CPhOH)] @ CH3CH2OH has been determined by X-raycrystallography. It crystallizes in the monoclinic system, space group P21/c, with Mr = 771.26 (C45H41CuO4P2),a = 0. 96413(19) nm, b= 1. 5780(3) nm, c = 2. 5426(5) nm, β = 100. 27(3)°, V= 3. 8065(13) nm3, The titlecompound consists of discrete copper (Ⅰ) bis(triphenylphosphine) salicylate molecules and ethanol solvate. EachCu is coordinated to two phosphorus atoms of triphenylphosphine ligands and one of carboxylate oxygens in a trigonalplanar geometry. In the solid, the intramolecular hydrogen bond and extensive intermolecular interaction connecting(PPh3) 2Cu(O2CPhOH) molecules and ethanol solvate form hydrogen bonds network which stabilize the crystalstructure. |
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| Keywords: | triphenylphosphine ligand crystal structure copper (Ⅰ) complex trigonal geometryhydrogen bond |
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