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Crystal structure of aquo (hydroxo) (ethylenediaminetetraacetato) sodium(I) tin(IV), NaSn(OH)(edta)(H2O)
Authors:Chantal Brouca-Cabarrecq  Bertrand Marrot  Alain Mosset
Affiliation:(1) Centre d'Elaboration de Matériaux et d'Etudes Structurales du CNRS, 29 rue Jeanne Marvig, 31055 Toulouse, France
Abstract:NaSn(OH)(edta)(H2O) is monoclinic, space groupP21/c, witha=9.747(3)Å,b=9.121(3)Å,c=16.430(6)Å, beta=98.69(4)°, Å3, andZ=4. The coordination environment of Sn(IV) is a capped octahedron. Sn–O distances range from 1.990(6)Å to 2.351(7)Å. Na(I) is five coordinated to three different edta molecules. Na–O distances range from 2.283(9)Å to 2.414(7)Å. The edta ligand presents the E, G/R conformation. The crystal structure is composed of sheets parallel to (001): inside a sheet Sn(OH)(edta) molecules are connected to each other by the Na(I) interactions.
Keywords:Tin(IV) sodium(I) complex  ethylenediaminetetraacetic acid  crystal structure
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