| 含西佛碱键的多羟基树脂的合成及对硼酸的吸附性能 |
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| 引用本文： | 钱国强,林雪.含西佛碱键的多羟基树脂的合成及对硼酸的吸附性能[J].离子交换与吸附,1995,11(1):45-53. |
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| 作者姓名： | 钱国强 林雪 |
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| 作者单位： | 南开大学高分子化学研究所 |
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| 摘 要： | 分别用亲水性的聚乙烯胺和疏水性的聚苯乙烯为载体，合成了一系列含不同长度间隔臂的多羟基螯合树脂，并讨论了树脂对硼酸的吸附、洗脱性能，结果表明树脂在中性、弱酸性条件下可较好地吸附硼酸；吸附速率与载体的亲水性和间隔壁长度有关；测定了吸附反应表观活化能以及吸附硼酸后可用０．５Ｎ盐酸洗脱。
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| 关 键 词： | 硼酸 吸附 多羟基树脂 洗脱 |
Synthesis and Adsorption Properties for Boris Acid of Polyghdroxy Chelaing Resins Containing Schiff Base Bond |
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| Qian Guoqiang, Lin Xue, Yang Yizhong ,He Binglin.Synthesis and Adsorption Properties for Boris Acid of Polyghdroxy Chelaing Resins Containing Schiff Base Bond[J].Ion Exchange and Adsorption,1995,11(1):45-53. |
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| Authors: | Qian Guoqiang Lin Xue Yang Yizhong He Binglin |
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| Abstract: | Polyhydroxy resins containing Schiff base bond with various spacers were synthesized based on cross-linked polyvinyl amine and polystyrcne matrix, and the adsorption-desorption properties for boric acid were also discussed. It showed that the resins can adsorb boric acid under neutral or weakly acid conditions; the adsorption rate constant usually increased with increase of spacer length and hydrophilicity of the matrix; the apparent activation energy and adsorption isothermal curve were determined. The boric acid adsorbed on resins can be eluted with 0.5NHCl. |
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| Keywords: | Boric acid Adsorption Spacer arm Polyhydroxy resin |
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