Synthesis and X-ray crystal structure of an anionic heteronuclear metallamacrocyclic triangle |
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Authors: | Vicente José Chicote María-Teresa Alvarez-Falcón Miguel M Jones Peter G |
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Institution: | Grupo de Quimica Organometalica, Departamento de Quimica Inorganica, Universidad de Murcia, Aptdo. 4021, 30071 Murcia, Spain. jvs1@um.es |
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Abstract: | trans-Pt(Ctriple bond]C(Ar)Ctriple bond]CH)2(PMe3)2](Ar = C(6)Me(4)-3,4,5,6) (1) reacts with PPNAu(acac)(2)](Hacac = acetylacetone; 1 : 1.16 molar ratio; PPN = (Ph3P)2N) to give PPN(AuPt(PMe3)2]2)(mu-Ar(Ctriple bond]C)2)3] (2) the crystal structure of which showed the anions as quasi equilateral triangles stacked parallel to each other through C-HAu interactions, resulting in channels of rhombic cross-section. |
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