|
|||||
|
|
Kinetic resolution of allylic alcohols via stereoselective acylation catalyzed by lipase PS-30 |
|
| Authors: | Peiran Chen Peng Xiang |
| Affiliation: | a School of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 Renmin Road North, Songjiang District, Shanghai 201620, China b Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, CAS, Shanghai 200032, China |
| Abstract: | By using lipase PS-30 as catalyst, the kinetic resolution of a series of racemic allylic alcohols has been achieved via stereoselective acylation. The value of kinetic enantiomeric ratio (E) reached up to 968. Substituent effect is briefly discussed. |
| Keywords: | Allylic alcohols Lipase PS-30 Kinetic resolution Stereoselective acylation Kinetic enantiomeric ratio (E) |
| 本文献已被 ScienceDirect 等数据库收录！ | |