New pathway for the disproportionation of hydrothiochromenes and structural studies of the resulting compounds |
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| Authors: | V. G. Kharchenko A. P. Kriven'ko O. V. Fedotova I. Ya. Evtushenko A. A. Shcherbakov G. G. Aleksandrov Yu. T. Struchkov |
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| Affiliation: | (1) N. G. Chernyshevskii Saratov State University, 410601 Saratov;(2) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, 117312 Moscow |
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| Abstract: | A new pathway for the disproportionation of hydrothiochromenes under the influence of protic acids, which consists in intermolecular hydride transfer of a hydrogen from the alicycle and leads to the development of a hydrothiochroman, was developed. Correlation results that confirm the structures and conformational peculiarities of the resulting compounds were obtained by PMR spectroscopy and x-ray diffraction analysis.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1337–1341, October, 1980. |
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