Synthesis, structure, and spectroscopy of an oxodiiron(II) complex |
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| Authors: | Eckert Nathan A Stoian Sebastian Smith Jeremy M Bominaar Emile L Münck Eckard Holland Patrick L |
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| Affiliation: | Department of Chemistry, University of Rochester, Rochester, New York 14627, USA. |
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| Abstract: | Bridging oxo species are important in the synthetic and biological chemistry of iron, and are found with iron oxidation states from +2 to +4. We report the first oxodiiron(II) complex that has been crystallographically characterized. It has been examined by NMR, IR, and M?ssbauer spectroscopies as well as density-functional calculations. |
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