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Anodic treatment of steel 40Kh in a 35-% sulfuric acid electrolyte containing chloride ions
Authors:Yu. A. Ivashkin
Affiliation:(1) Bryansk State Engineering and Technological Academy, Bryansk, Russia
Abstract:Anodic dissolution of steel 40Kh in a sulfuric acid electrolyte containing Cl ions is studied by analyzing the experimental dependence of anodic current on the specimen potential. The dependences of the critical passivation current, anodic current at –0.15 to 0.55 V (Ag/AgCl), and passivation current on the concentration of Cl ions (c) are determined. The maximum value of c for the passivation at 0.55–1.6 V (Ag/AgCl) is refined. The dependence of the specimenrsquos steady-state potential on c is determined and its decrease is related to an abrupt increase in the anodic current at the passivation potentials.Translated from Elektrokhimiya, Vol. 41, No. 3, 2005, pp. 371–374.Original Russian Text Copyright © 2005 by Ivashkin.
Keywords:anodic treatment of steel  etching rate  oxide film  passivation  steady-state potential
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