Highly enantioselective hydrovinylation of alpha-alkyl vinylarenes. an approach to the construction of all-carbon quaternary stereocenters |
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| Authors: | Shi Wen-Jian Zhang Qi Xie Jian-Hua Zhu Shou-Fei Hou Guo-Hua Zhou Qi-Lin |
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| Institution: | State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China. |
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| Abstract: | The highly enantioselective hydrovinylation of alpha-alkyl vinylarenes was realized by using nickel complexes of chiral spiro phosphoramidite ligands. The method provided a new approach to the construction of chiral all-carbon quaternary centers. |
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