| 配合物[Eu(Ⅲ)(TFPB)3bpy]的晶体结构和发光性质(英) |
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| 引用本文： | 郭俊芳,张洪杰,符连社,孟庆国. 配合物[Eu(Ⅲ)(TFPB)3bpy]的晶体结构和发光性质(英)[J]. 无机化学学报, 2004, 20(5): 543-546 |
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| 作者姓名： | 郭俊芳 张洪杰 符连社 孟庆国 |
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| 作者单位： | 中国科学院长春应用化学研究所稀土化学与物理重点实验室,长春,130022 |
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| 基金项目： | 国家自然科学基金(No.20171043，No.20131010，No.20121701)，973项目(No.G1998061307)，863项目(No.2002AA302105,2002AA324080)资助项目。 |
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| 摘 要： | The crystal structure of Eu(TFPB)3bpy [TFPB: 4,4,4-trifluoro-1-phenyl-1,3- butanedione, bpy: 2,2′-bipyridyl] has been determined by single crystal X-ray diffraction and the coordination geometry of Eu atom is a square antiprism. The complex can give the characteristic luminescence of Eu3+ upon UV excitation. CCDC: 224879.
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| 关 键 词： | 晶体结构 稀土配合物 发光性质 |
Crystal Structure and Luminescent Properties of the Complex [Eu(Ⅲ)(TFPB)3bpy] |
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| GUO Jun-Fang,ZHANG Hong-Jie,FU Lian-She and MENG Qing-Guo. Crystal Structure and Luminescent Properties of the Complex [Eu(Ⅲ)(TFPB)3bpy][J]. Chinese Journal of Inorganic Chemistry, 2004, 20(5): 543-546 |
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| Authors: | GUO Jun-Fang ZHANG Hong-Jie FU Lian-She MENG Qing-Guo |
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| Affiliation: | Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022,Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022,Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 and Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 |
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| Abstract: | The crystal structure of Eu(TFPB)3bpy [TFPB:4,4,4-trifluoro-l-phenyl-1,3- butanedione, bpy:2,2'-bipyridyl]has been determined by single crystal X-ray diffraction and the coordination geometry of Eu atom is a square antiprism. The complex can give the characteristic luminescence of Eu3+ upon UV excitation. CCDC: 224879. |
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| Keywords: | crystal structure rare earth complex luminescence properties |
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