Indium(III) chloride-sodium borohydride system: a convenient radical reagent for an alternative to tributyltin hydride system |
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| Authors: | Inoue Katsuyuki Sawada Akemi Shibata Ikuya Baba Akio |
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| Institution: | Department of Molecular Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamada-Oka, Suita, Osaka 565-0871, Japan. |
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| Abstract: | The indium hydride generated from NaBH4 and InCl3, is a promising candidate of alternative to Bu3SnH. In particular, the catalytic performance of InCl3 in the dehalogenation of alkyl and aryl halides, intramolecular cyclization and intermolecular coupling reaction are noteworthy. |
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