| 四-α-(2，2，4-三甲基-3-戊氧基)酞菁金属配合物(M=Co，Ni，Cu，Zn)的合成与光谱性质(英) |
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| 引用本文： | 江舟,陈耐生,王俊东,黄金陵. 四-α-(2，2，4-三甲基-3-戊氧基)酞菁金属配合物(M=Co，Ni，Cu，Zn)的合成与光谱性质(英)[J]. 无机化学学报, 2005, 21(12): 1891-1896 |
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| 作者姓名： | 江舟 陈耐生 王俊东 黄金陵 |
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| 作者单位： | 福州大学化学化工学院,功能材料研究所,福州,350002 |
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| 基金项目： | 福建省自然科学基金资助项目(No.E0310007)。 |
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| 摘 要： | A series of [tetra-α-(2,2,4-tirmethyl-3-pentoxy) phthalocyaninato] metal complexes(M=Co, Ni, Cu, Zn)were prepared by cyclotetramerization of 3-(2,2,4-tirmethyl-3-pentoxy)phthalonitrile with corresponding anhydrous metal salts， using 1.8-diazabicyclo[5.4.0] undec-7-ene (DBU) as the catalyst. HPLC analysis shows that one isomer predominates in the product of nickel complex, while at least two main constitutional isomers exist in the product of other metal complexes. The complexes (in the form of mixture of constitutional isomers) were characterized by elemental analyses, MS, IR and UV-Vis spectroscopy.
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| 关 键 词： | 酞菁金属配合物； 光谱性质； 构造异构体 |
| 文章编号： | 1001-4861(2005)12-1891-06 |
| 收稿时间： | 2005-05-23 |
| 修稿时间： | 2005-07-26 |
Synthesis and Spectroscopic Property of [tetra-α-(2,2,4-tirmethyl-3-pentoxy) Phthalocyaninato] Metal Complexes (M=Co, Ni, Cu, Zn) |
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| JIANG Zhou,CHEN Nai-Sheng,WANG Jun-Dong and HUANG Jin-Ling. Synthesis and Spectroscopic Property of [tetra-α-(2,2,4-tirmethyl-3-pentoxy) Phthalocyaninato] Metal Complexes (M=Co, Ni, Cu, Zn)[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(12): 1891-1896 |
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| Authors: | JIANG Zhou CHEN Nai-Sheng WANG Jun-Dong HUANG Jin-Ling |
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| Affiliation: | Institute of Research on Functional Materials, Fuzhou University, Fuzhou 350002,Institute of Research on Functional Materials, Fuzhou University, Fuzhou 350002,Institute of Research on Functional Materials, Fuzhou University, Fuzhou 350002 and Institute of Research on Functional Materials, Fuzhou University, Fuzhou 350002 |
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| Abstract: | A series of [tetra-α-(2,2,4-tirmethyl-3-pentoxy) phthalocyaninato] metal complexes(M=Co, Ni, Cu, Zn)were prepared by cyclotetramerization of 3-(2,2,4-tirmethyl-3-pentoxy)phthalonitrile with corresponding anhydrous metal salts, using 1.8-diazabicyclo[5.4.0] undec-7-ene (DBU) as the catalyst. HPLC analysis shows that one isomer predominates in the product of nickel complex, while at least two main constitutional isomers exist in the product of other metal complexes. The complexes (in the form of mixture of constitutional isomers) were characterized by elemental analyses, MS, IR and UV-Vis spectroscopy. |
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| Keywords: | phthalocyaninato metal complex spectroscopic property constitutional isomer |
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