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Polarity determination of wurtzite-type crystals using hard x-ray photoelectron diffraction
Authors:Jesse R. Williams  Masaaki Kobata  Igor Pis  Eiji Ikenaga  Takeharu Sugiyama  Keisuke Kobayashi  Naoki Ohashi
Affiliation:1. International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan;2. NIMS Saint-Gobain Research Center of Excellence for Advanced Materials, NIMS, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan;3. Beamline Station, National Institute for Materials Science (NIMS), SPring-8, 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan;4. Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, V Hole?ovi?kách 2, 18000 Prague 8, Czech Republic;5. Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
Abstract:The surface structure of a single-crystal ZnO wafer was studied by angle-resolved x-ray photoelectron spectroscopy (ARXPS) using synchrotron radiation. As a result, well-defined x-ray photoelectron diffraction (XPD) patterns were obtained for the (0001) and (0001¯) polar surfaces using the photoemission from the Zn 2p3/2 and O 1s core levels. The XPD patterns were indexed assuming forward scattering of photoelectrons by neighboring ions. Further, the XPD patterns for the (0001) and (0001¯) surfaces were different from each other, indicating the possibility for using the XPD technique for polarity determination.
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