Influence of calcination temperature on surface acidity of the solid superacid of sulfated alumina |
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Authors: | Hiromi Matsuhashi Daishi Sato and Kazushi Arata |
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Institution: | (1) Hokkaido University of Education, 1-2 Hachiman-cho, Hakodate 040-8567, Japan |
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Abstract: | The acidity of sulfated alumina catalysts was studied by analyzing DTG and heat of Ar adsorption together with the isomerization of pentane. The initial acid sites were Brönsted-type, and converted into Lewis-type upon increasing the pretreatment temperature. The heat of Ar adsorption of the most active sulfated alumina was 18.9 kJ mol–1, this value being a little smaller than that of sulfated zirconia (23.6 kJ mol–1).This revised version was published online in December 2005 with corrections to the Cover Date. |
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Keywords: | Sulfated alumina solid superacid acid strength Lewis acid heat of Ar adsorption |
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