Über neue Siliciumschichtverbindungen aus Calciumdisilicid |
| |
| Authors: | Edwin Hengge D. Schiefer A. Baumegger |
| |
| Affiliation: | (1) Institut für Anorganische Chemie, Technische Universität Graz, A-8010 Graz, Österreich |
| |
| Abstract: | Summary (SiCl)n is a high polymeric compounds with a layered structure, yielded from the layer lattice CaSi2 with ICl. New compounds were formed on the surface of these layers by action of polyvalent alcohols like ethanediol, 1,3-propanediol, 1,4-butanediol and glycerine. BET and IR measurements and the analysis show that all OH groups of the alcohols react with the Si-Cl linkage on one layer, forming a handle structure. (SiCl)n also reacts with trimethylaluminum, forming a polymeric methylsilicon Si(CH3)n.Herrn Prof. Dr. J. Schurz zum 65. Geburtstag gewidmet. |
| |
| Keywords: | Laminated structure of silicon compounds Alkoxypolysilanes Calcium disilicide |
| 本文献已被 SpringerLink 等数据库收录！ |
|
