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Determination of Mass Coefficients of Ions in a Quantitative Analysis of the Effect of Natural Convection on Electrochemical Processes
Authors:D. A. Bograchev  V. M. Volgin  A. D. Davydov
Affiliation:(1) Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia;(2) Tula State University, pr. Lenina 92, Tula, 300600, Russia
Abstract:Methods for calculating buoyancy forces in multicomponent electrochemical systems using relative ion mass coefficients are analyzed. An approximate method for determining ion mass coefficients using the available reference data on the concentration dependences of densities of individual substance solutions is developed. Ionic mass coefficients, found using this method, are tabulated. These can be used for determining buoyancy forces in electrochemical systems of various compositions.
Keywords:natural convection  ionic transfer  buoyancy force  mass coefficients of substances
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