Single crystal EPR study of VO(II)-doped cadmium potassium phosphate hexahydrate: A substitutional incorporation |
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Authors: | I Sougandi T M Rajendiran R Venkatesan and P Sambasiva Rao |
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Institution: | (1) Department of Chemistry, Pondicherry University, R V Nagar, Kalapet, 605 014 Pondicherry, India |
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Abstract: | Single crystal EPR studies of VO(II)-doped cadmium potassium phosphate hexahydrate (CPPH) have been carried out at room temperature.
The angular variation spectra in the three orthogonal planes indicate that the paramagnetic impurity has entered the lattice
only substitutionally in place of Cd(II). Spin Hamiltonian parameters have been obtained from single crystal data. Powder
spectra show a set of eight parallel and perpendicular features indicating the presence of only one site. The admixture coefficients
have been calculated from the data, which agree well with the literature values. |
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Keywords: | EPR VO(II) cadmium potassium phosphate hexahydrate substitutional incorporation spin-Hamiltonian parameters |
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